Crowd Science is a new comer among user research services that allow you to prompt small sets of users to participate in questionnaires while they're browsing your site.

Crowd Science Demographics is a new analytics service that builds detailed reports on the demographics and attitudes of website audiences. By surveying a small number visitors with carefully constructed questionnaires, Crowd Science Demographics is able to build comprehensive audience profiles that give publishers a deep understanding of their audience.

http://www.crowdscience.com/